Significance Of Wave Function
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Significance of Wave Function
The symbol
occurs in the wave equation as the amplitude function which needs explanation for better understanding of the electron behavior. Does the amplitude function
have any physical significance like the one we attach to other waves? The straight-forward answer to this equation is No. That is
has only mathematical significance an do not attach any physical significance to
,.
as a wave function must obey the following condition if it is to give meaningful results:
(i)
must be single valued, i.e. it must have only one definite value at a particular point in space.
(ii)
must be continuous at all points in space, i.e. there must not be sudden changes in the values of
when its variables are changed.
(iii)
must have a finite value over the space that the electron can occupy.
(iv)
must be normalized, i.e., the probability of finding the electron in the space under consideration must be unity.
(v)
must become zero at infinity.
This means that of all the values of
obtained by solving Schrödinger wave equation, only those values of
are accepted which obey the above condition. Thus only acceptable values of
have significance.
The significant values of
are called Eigen function or wave function. Eigen function give significant values of the total energy of Electron (E) called Eigen values. These Eigen values correspond to the discrete energy levels as postulated by Niels Bohr.
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(i)

(ii)


(iii)

(iv)

(v)

This means that of all the values of



The significant values of

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