The Partition Function
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The Partition Function
According to Boltzmann distribution law (Eqn. 2.7.18), the fraction of molecules which in the most problem state at temperature T possesses the energy

Where ni is the number fo molecules having energy


The denominator of the above equation which gives the sum of the terms

Thus

The partition function is so called because it indicates the particles, are distributed among the various energy states.
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